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SynopsisProtonolysis of the title compounds involves rate-determining proton transfer to the substrate. Subsequent isomerization is dissociative. Activation volumes for the two processes have opposite signs. A new kinetic β-hydrogen accelerating effect for isomerization favoring the fluxionality of a T-shaped 14-electron intermediate is reported.AbstractAbstract ImageProtonolysis of the complexes SynopsisProtonolysis of the title compounds involves rate-determining proton transfer to the substrate. Subsequent isomerization is dissociative. Activation volumes for the two processes have opposite signs. A new kinetic β-hydrogen accelerating effect for isomerization favoring the fluxionality of a T-shaped 14-electron intermediate is reported.AbstractProtonolysis of the complexes cis-[PtR2(PEt3

A tax litigation concerning the value of nontraded financial instruments is impregnated by uncertainty. The aim of this paper is to study how uncertainty inherent in financial valuation models is discursively and rhetorically handled and constructed by the litigating parties aswell as the court. A discourse analysis guided by the notion of hedging is conducted on The Swedish Tax Agency v. PwC (201

Wildfires are a major driver of ecosystem development and contributor to carbon emissions in boreal forests. We analyzed the contribution of fires of different fire size classes to the total burned area and suggest a novel fire characteristic, the characteristic fire size, i.e., the fire size class with the highest contribution to the burned area, its relation to bioclimatic conditions, and intra-

Popular Abstract in Swedish Ortopedteknik i utvecklings-länder, hur funkar det? Hur fungerar den ortopedtekniska servicen i länder präglade av fattigdom och inbördeskrig? Lina Magnusson disputerade i november med en avhandling om ortopedteknisk service i utvecklingsländer. Lina Magnusson är den första kvinnliga ortopedingenjören som disputerar i Sverige. Hennes avhandling beskriver patienters rAim: The overall aim of this thesis was to generate further knowledge about prosthetic and orthotic services in developing countries. In particular, the thesis focused on patient mobility and satisfaction with prosthetic and orthotic devices, satisfaction with service delivery, and the views of staff regarding clinical practice and education. Methods: Questionnaires, including QUEST 2.0, were use

En familj har traditionellt sett bestått av en moder, en fader och ett antal barn. Det innebär att lagstiftningen inom familjerätten är utformad för att passa dessa omständigheter. Lagstiftarna har arbetat utifrån antagandet att de familjer som skulle påverkas av deras lagstiftning skulle vara av den traditionella sorten och att deras lagstiftning därför skulle vara fullt tillräcklig. Det har sagTraditionally families have been made up of a mother, a father and any number of children. This means that the legislation in this area has been made to fit those circumstances. The legislators have worked under the assumption that the families affected by their policies would be of the traditional kind and therefore their policies would be sufficient. It has been said that the legislation in a

This report presents how far NCC current VDC tools and methods in building construction can be implemented in road and infrastructure projects also what new tools, methods that can be created helped by pre-selected software’s. VDC is well developed within the construction of building and research and resources in the field have been spent under a longer period of time unlike in road and infrastruc

Investeringsrådgivning är när en personlig rekommendation avseende ett finansiellt instrument lämnas till en kunde. Det finns inga begränsningar i hur det ska gå till, utan det kan både genom ett fysiskt möte och via ett automatiskt verktyg. Vid investeringsrådgivning finns det omfattande krav som måste uppfyllas. Kraven handlar huvudsakligen om information som ska lämnas till kund, en bedömning aProviding investment advice is the act of giving a personalized investment advice to a client in relation to a financial instrument. There is no set form for how investment advice is provided, it can be done by a person in a meeting, as well as by an automated tool. The legislation that must be complied with while providing investment advice is extensive. The legislation mainly stipulates three re

Popular Abstract in Swedish Pankreascancer, cancer i bukspottkörteln, är den fjärde vanligaste orsaken till död i cancer och årligen insjuknar cirka 1000 patienter i Sverige. Överlevnaden är kort med en 5-årsöverlevnad på endast 6 procent. Pankreascancer orsakar, förutom lidande, också betydande kostnader för såväl den medicinska vården, som förluster för samhället, exempelvis i form av förtida döBackground: Pancreatic cancer is the fourth leading cause of cancer-related death. Only about 6% of patients are alive 5 years after diagnosis. One reason for this low survival rate is that most patients are diagnosed at a late stage, when the tumor has spread to surrounding tissues or distant organs. Less than 20% of cases are diagnosed at an early stage that allows them to undergo potentially cu

BACKGROUND: Cancer has consequences not only for the sick person but also for those who have a close relationship with that person. Greater knowledge about how family members manage the situation in the period immediately following the diagnosis means greater opportunity to provide the best possible support for the family. The purpose of this study was to explore management strategies that family

Det kan vara problematiskt att hålla förhör och åberopa förhör med barn som bevittnat våld i nära relation. När barnet inte uppnått en viss ålder och mognad så att barnets medgivande till förhör är tillräckligt, ska barnet enligt föräldrabalkens bestämmelser företrädas av, vanligtvis, vårdnadshavaren. Åldersgränsen för när barn uppnått en tillräcklig ålder och mognad så att denne själv kan ta till, can be problematic. When the child doesn´t reach a certain age and maturity so the child's consent to interrogation is sufficient, the child will under föräldrabalkens provisions represented by, usually, the guardian. The age limit for when the children reached a sufficient age and maturity, so they can take advantage of their right appears as a general rule be fifteen years. If the child wi

Cloud computing has become one of the fastest growing segments of the IT industry. In the wake of this success, cloud based Enterprise Resource Planning (ERP) systems have emerged as an alternative to the traditional ERPs for companies to plan and manage their resources. These systems require low upfront investments and can rapidly be deployed, as they and their underlying infrastructure are provi

Popular Abstract in Swedish För drygt ett decennium sedan beslutade EU:s dåvarande tolv medlemsstater att upprätta ett gemensamt europeiskt medborgarskap för unionens invånare. Alltsedan dess har det europeiska medborgarskapet varit en omdiskuterad och kontroversiell, men för den breda allmänheten tämligen okänd, innovation i den europeiska integrationen. I Medborgarskap efter nationalstaten ? ettThis thesis is an attempt to formulate a constructive proposal for the ongoing establishment of a post-national European citizenship in the European Union. To the extent that the proposal is post-national, the ambition is to re-conceptualise the idea and ideal of citizenship in a new historical setting. To the extent that the proposal is constructive, the ambition is to develop and employ a method

The future of EU lies in the SEE or to rephrase, the future of the SEE lies in the EU. This is considered to be the case as the SEE countries that are not yet EU-members have been promised future membership and are therefore considered the next potential EU members. As this scenario lies in the future of an EU expansion an interest of what lies in the past of these two regions rises. This interest

Den här uppsatsen diskuterar äktenskapet och dess okritiserade roll i den svenska familjerätten. Det huvudsakliga syftet med uppsatsen är att granska äktenskapet som en statligt reglerad samlevnadsform. Detta görs genom att granska äktenskapets historia, gällande rätt, äktenskapets funktioner och lagstiftarens överväganden vid reglering av intima relationer. Uppsatsen har också ett kritiskt anslagThis paper discusses marriage and its uncriticized role in Swedish family law. The main purpose of the essay is to examine marriage as a state regulated form of intimate relation between individuals. The essay examines the history of marriage, the applicable law, the function of marriage and the legislator’s considerations when it comes to legislation concerning intimate relations. This paper als

Agricultural intensification has led to the homogenization of the landscape and the disappearance of diverse habitats with rich flower resources that are important for pollinating insects. The main insect pollinators, by far, are bees. And while honey bees (Apis mellifera) are the best known, there are also hundreds of other species of bees that contribute to pollination services. Due to their for

En aktuell debatt i svensk politik är hushållens växande skulder, framför allt i storstadsområdena. Förslag har lagts fram från Finansinspektionen och Sveriges Riksbank om amorteringskrav, skuldkvotstak och sänkt ränteavdrag. Detta för att hämma en eventuellt fortsatt ökning av hushållens skulder. Den svenska hushållssektorns ökande skuldsättning tillskrivs främst de lägre kostnaderna för bolån soA current topic in Swedish politics is the increasing household debt, particularly in the metropolitan areas. The Swedish Central Bank and the Financial Supervisory Authority have made proposals for several policies, to inhibit a continued growth of the household debt. These policies include introducing amortization requirements, a debt-to-income ratio limit and reduced home mortgage interest dedu

Trap roads are a part of the Swedish railway facility and resembles the safest front- and side protection at speed above 160 km/h. When designing Trap roads, some regulations needs to be followed. As these, in some cases, may be contradictory towards each other, the planners become somewhat insecure. The purpose of the master thesis has thenceforth been to clarify for the planners, as well as to w

Sammanfattning Inom konkursrätt kan vara av intresse för ett konkursbo att låta viss egendom utgå ur konkursboet i syfte att ge så god utdelning som möjligt till borgenärerna. Till exempel i de fall att egendomen är befäst med olika utgifter som kan bidra till att konkursboet får en minskad nettovinst. Genom NJA 2004 s. 777 har abandonering ansetts vara tillåtet i svensk rätt och det har sedan desSummary In swedish bankruptcy law, it may be in the interest of a bankruptcy estate have certain property in the bankruptcy assets removed to provide the best possible gain for the creditors. For instance, in certain cases the property may be secured with various expenses that may contribute to the bankruptcy estate receiving a reduced net profit. Through the legal precedent NJA 2004 s. 777, aband

This study investigates the validity of the Permanent Income Hypothesis (PIH) across seven countries from 1970 to 2021. Using Hall's random-walk model and Campbell and Mankiw’s IV model, I investigate if the consumption patterns align with the implications of the PIH and if there are differences between the countries studied. The analysis suggests evidence against the PIH, revealing deviat