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Protonolysis of Dialkyl and Alkylaryl Platinum(II) Complexes and Geometrical Isomerization of the Derived Monoorgano-Solvento Complexes: Clear-Cut Examples of Associative and Dissociative Pathways in Platinum Chemistry

SynopsisProtonolysis of the title compounds involves rate-determining proton transfer to the substrate. Subsequent isomerization is dissociative. Activation volumes for the two processes have opposite signs. A new kinetic β-hydrogen accelerating effect for isomerization favoring the fluxionality of a T-shaped 14-electron intermediate is reported.AbstractProtonolysis of the complexes cis-[PtR2(PEt3

Process Region Characteristics During Fast Crack Growth

The conditions for crack arrest at speeds down to below 0.1 of the Rayleigh-wave speed are examined. The elastic energy release rate is assumed to be balanced by the deformation work in a viscoplastic continua and the energy release rate in a fracture process region. Fractographic show that a small fraction of the surface is created through ductile rupture. Even though the fraction represents only

Unveiling the process of sustainable renovation

Renovation processes are complex and there is a risk of underestimating architectural, cultural, and social values in favor of exterior and interior upgrading, energy efficiency and financing. A synthesized, systematic process is needed for making decisions about renovation measures. The aim of this paper is to survey decision-making procedures aimed for sustainable renovation. We inventory existi

Navigating Implementation: A Grounded Theory Exploration of YAM with Professionals in Lund, Sweden

In response to escalating public health challenges, particularly concerning mental health issues among youth, manual-based interventions have gained prominence in Sweden. These interventions are increasingly seen as integral components of proactive measures to address the escalating rates of mental illness. This study focuses on the implementation of the evidence-based program Youth Awareness of M

A concept of space for building classification, product modelling, and design

Information about a building's spaces is of interest in every stage of the construction and facility management processes. An organisation1 or enterprise is located in and uses the building's spaces, and many of the building's spatial properties are determined on the basis of the user organisation's requirements. The definition of the concept “space” as applied in information systems for building