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Band-selective dynamics in charge-transfer excited iron carbene complexes

Ultrafast dynamics of photoinduced charge transfer processes in light-harvesting systems based on Earth-abundant transition metal complexes are of current interest for the development of molecular devices for solar energy conversion applications. A combination of ultrafast spectroscopy and first principles quantum chemical calculations of a recently synthesized iron carbene complex is used to eluc

A prescription for “nature” – The potential of using virtual nature in therapeutics

Many studies suggest that increased exposure to urban greenness is associated with better population health. Accessing nature can in some circumstances, however, be difficult, especially for individuals with mobility constraints. Therefore, a growing body of work is investigating the ways to replace the in vivo experience with forms of “virtual” contact, in order to provide these individuals with

The PDGF pathway in breast cancer is linked to tumour aggressiveness, triple-negative subtype and early recurrence

Purpose: The platelet-derived growth factor (PDGF) signalling pathway is often dysregulated in cancer and PDGF-receptor expression has been linked to unfavourable prognostic factors in breast cancer (e.g. ER negativity, high Ki67 and high grade). This study aimed to evaluate the expression of PDGFRα, PDGFRβ and ligand PDGF-CC in breast cancer in relation to molecular subtypes and prognosis. Method

FeII Hexa N-Heterocyclic Carbene Complex with a 528 ps Metal-To-Ligand Charge-Transfer Excited-State Lifetime

The iron carbene complex [FeII(btz)3](PF6)2 (where btz = 3,3′-dimethyl-1,1′-bis(p-Tolyl)-4,4′-bis(1,2,3-Triazol-5-ylidene)) has been synthesized, isolated, and characterized as a low-spin ferrous complex. It exhibits strong metal-To-ligand charge transfer (MLCT) absorption bands throughout the visible spectrum, and excitation of these bands gives rise to a 3MLCT state with a 528 ps excited-state l

Extending working life: experiences from Sweden, 1981–2011

Population ageing is making it increasingly diffcult for countries to sustain their current levels social welfare transfers from the economically active population to the dependent elderly. To meet this challenge, the Swedish government has implemented various reforms since the 1990s aimed at reducing incentives to take early retirement. However, a critical question has emerged in response to thes

Adaptable Recovery Behaviors in Robotics : A Behavior Trees and Motion Generators (BTMG) Approach for Failure Management

In dynamic operational environments, particularly in collaborative robotics, the inevitability of failures necessitates robust and adaptable recovery strategies. Traditional automated recovery strategies, while effective for predefined scenarios, often lack the flexibility required for on-the-fly task management and adaptation to expected failures. Addressing this gap, we propose a novel approach

Impact of antenna pattern directivity on near-field focusing of planar array in large intelligent surface applications

Near-field focusing (NFF) is a fundamental enabler for a broad spectrum of applications utilizing large intelligent surfaces (LIS) within sub-10 GHz frequency bands. This paper investigates the impact of element pattern on NFF properties, when the LIS array is a large planar array. The NFF properties of maximum received power, focal width, and focal depth are analyzed for three typical antenna pat

Birth prevalence of cleft lip and/or palate - a register study of all children born in Sweden years 2000-2020

This study investigated the birth prevalence of cleft lip and/or palate (CL/P) in Sweden between 2000 and 2020 using data from the Swedish National Medical Birth Register, which includes over 97% of children born in the country, and its subregister the National Register of Congenital Anomalies. The dataset included 2,230,771 anonymized children, with the variables year of birth, sex and diagnoses

Wideband single-layer D-band patch antenna with parasitic elements and superstrate loading

This paper proposes a D-band patch antenna featuring four parasitic elements and a loaded superstrate layer. Inspired by a previous parasitic patch antenna design, the new structure is synthesized from scratch using characteristic mode analysis. The new design features different operating principles that enable low-cost single-layer fabrication on PCB HDI technology, while retaining wideband opera

Real-Time Near-Field mmWave Measurements Using Screen-Printed Metasurfaces and IR Camera

This article elaborates on a technique for rapid real-time imaging of millimeter-wave (mmWave) power density over surfaces of several wavelengths in size. The approach involves using a screen-printed metasurface equipped with elements designed for absorption of mmWaves, along with an infrared (IR) camera to monitor temperature changes due to the absorption. By modulating the transmitted signal and

Dust in the arctic : a brief review of feedbacks and interactions between climate change, aeolian dust and ecosystems

Climatic feedbacks and ecosystem impacts related to dust in the Arctic include direct radiative forcing (absorption and scattering), indirect radiative forcing (via clouds and cryosphere), semi-direct effects of dust on meteorological parameters, effects on atmospheric chemistry, as well as impacts on terrestrial, marine, freshwater, and cryospheric ecosystems. This review discusses our recent und

Biofilm-dispersed pneumococci induce elevated leukocyte and platelet activation

INTRODUCTION: Streptococcus pneumoniae (the pneumococcus) effectively colonizes the human nasopharynx, but can migrate to other host sites, causing infections such as pneumonia and sepsis. Previous studies indicate that pneumococci grown as biofilms have phenotypes of bacteria associated with colonization whereas bacteria released from biofilms in response to changes in the local environment (i.e.

Deeper Insight of the Conformational Ensemble of Intrinsically Disordered Proteins

It is generally known that, unlike structured proteins, intrinsically disordered proteins, IDPs, exhibit various structures and conformers, the so-called conformational ensemble, CoE. This study aims to better understand the conformers that make up the IDP ensemble by decomposing the CoE into groups separated by their radius of gyration, Rg. A common approach to studying CoE for IDPs is to use low

Proton Beam APerture MoniTor instrument design and overview for the Commissioning and Operation of ESS High Power Beam on Target

This paper presents a detector developed to protect the ESS spallation target. The detector is installed to receive a proton beam that has a peak current of 62.5 mA, an average power of 5 MW, and energy up to 2 GeV. It is designed to detect any part of the proton beam that goes outside a defined aperture, which is deemed as an errant beam condition. This detector is mainly used for machine protect

Tensor decomposition of EEG signals for transfer learning applications

We address the recognized person-to-person Brain–Computer Interface (BCI) calibration problem and tackle session-dependency through the use of unsupervised canonical polyadic (CP) tensor decomposition. For a motor imagery task, the approach reveals universal structures within EEG data, common between subjects and prominent for a certain task. Further, we develop a novel similarity measure that inc

Storage Assignment Using Nested Metropolis Sampling and Approximations of Order Batching Travel Costs

The Storage Location Assignment Problem (SLAP) is of central importance in warehouse operations. An important research challenge lies in generalizing the SLAP such that it is not tied to certain order-picking methodologies, constraints, or warehouse layouts. We propose the OBP-based SLAP, where the quality of a location assignment is obtained by optimizing an Order Batching Problem (OBP). For the

A reconfigurable RF front-end for 5G direct sampling receivers with an optimized calibration scheme

This paper presents a reconfigurable radio frequency front-end (RFFE) tailored for direct RF sampling receivers operating within Frequency Range 1 (FR-1) of the 5G spectrum. It consists of a balun-LNA, a noise-cancelling, current-reuse, Q-enhanced filter, and a programmable gain amplifier (PGA). Fabricated in 22-nm FD-SOI technology, the RFFE covers the entire frequency range from 1.7 to 6.4 GHz w

Risk of severe COVID-19 from the Delta and Omicron variants in relation to vaccination status, sex, age and comorbidities - surveillance results from southern Sweden, July 2021 to January 2022

We compared the risk of severe COVID-19 during two periods 2021 and 2022 when Delta and Omicron, respectively, were the dominating virus variants in Scania county, Sweden. We adjusted for differences in sex, age, comorbidities, prior infection and vaccination. Risk of severe disease from Omicron was markedly lower among vaccinated cases. It was also lower among the unvaccinated but remained high (