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Side-group switching between metal-to-ligand charge-transfer and metal-centered excited state properties in iron(II) N-heterocyclic carbene complexes

Fe(II) N-heterocyclic carbene (NHC) complexes have emerged over the last decade as a promising class of light-harvesting complexes for a variety of photochemical applications relying on the presence of high-energy excited states of mainly charge-transfer character with excited state lifetimes of tens of picoseconds or longer. Recent spectroscopic investigations have significantly refined the under

Tailoring the Photophysical Properties of a Homoleptic Iron(II) Tetra N-Heterocyclic Carbene Complex by Attaching an Imidazolium Group to the (CNC) Pincer Ligand─A Comparative Study

We here report the synthesis of the homoleptic iron(II) N-heterocyclic carbene (NHC) complex [Fe(miHpbmi)2](PF6)4 (miHpbmi = 4-((3-methyl-1H-imidazolium-1-yl)pyridine-2,6-diyl)bis(3-methylimidazol-2-ylidene)) and its electrochemical and photophysical properties. The introduction of the π-electron-withdrawing 3-methyl-1H-imidazol-3-ium-1-yl group into the NHC ligand framework resulted in stabilizat

Deep learning performance on MRI prostate gland segmentation : evaluation of two commercially available algorithms compared with an expert radiologist

PURPOSE: Accurate whole-gland prostate segmentation is crucial for successful ultrasound-MRI fusion biopsy, focal cancer treatment, and radiation therapy techniques. Commercially available artificial intelligence (AI) models, using deep learning algorithms (DLAs) for prostate gland segmentation, are rapidly increasing in numbers. Typically, their performance in a true clinical context is scarcely

Gas-Phase Anion Exchange for Multisegment Heterostructured CsPb(Br1xClx)3 Perovskite Nanowires

Metal-halide perovskites (MHPs) are promising as active optoelectronic materials for a diverse range of devices. Anion exchange is a post-growth modification of MHP materials that allows tuning of the band gap and crystal structure by exposure to alternative halides, normally using solution methods. Here, low temperature gas-phase anion exchange for the conversion of CsPbBr3 nanowires (NW) into Cs

Competing dynamics of intramolecular deactivation and bimolecular charge transfer processes in luminescent Fe(iii) N-heterocyclic carbene complexes

Steady state and ultrafast spectroscopy on [FeIII(phtmeimb)2]PF6 (phtmeimb = phenyl(tris(3-methylimidazol-2-ylidene))borate) was performed over a broad range of temperatures. The intramolecular deactivation dynamics of the luminescent doublet ligand-to-metal charge-transfer (2LMCT) state was established based on Arrhenius analysis, indicating the direct deactivation of the 2LMCT state to the doubl

Anion-Specific Adsorption of Carboxymethyl Cellulose on Cellulose

Integration of fiber modification step with a modern pulp mill is a resource efficient way to produce functional fibers. Motivated by the need to integrate polymer adsorption with the current pulping system, anion-specific effects in carboxymethylcellulose (CMC) adsorption have been studied. The QCM-D adsorption experiments revealed that CMC adsorption to the cellulose model surface is prone to an

Cystatin C–Based Equation to Estimate GFR without the Inclusion of Race and Sex

BACKGROUNDThe accuracy of estimation of kidney function with the use of routine metabolic tests, such as measurement of the serum creatinine level, has been controversial. The European Kidney Function Consortium (EKFC) developed a creatinine-based equation (EKFC eGFRcr) to estimate the glomerular filtration rate (GFR) with a rescaled serum creatinine level (i.e., the serum creatinine level is divi

Malmö Breast ImaginG database: objectives and development

PurposeWe describe the design and implementation of the Malmö Breast ImaginG (M-BIG) database, which will support research projects investigating various aspects of current and future breast cancer screening programs. Specifically, M-BIG will provide clinical data to: 1. investigate the effect of breast cancer screening on breast cancer prognosis and mortality; 2. develop and validate the use of a

Overlapping Trade Agreements: Stepping Stones or Stumbling Blocks?

This paper analyzes the effect of overlapping Trade blocs on Trade Facilitation. Using the time, documents and costs incurred as trade facilitation indicators, simulations show interesting yet important effects of an increase in Regional Trade Agreements on trade costs. The results suggest that when it comes to increasing regional trade agreements by 1%, costs are associated with an increase via t

Ferroelectricity in ultrathin HfO2-based films by nanosecond laser annealing

Nonvolatile memory devices based on ferroelectric HfxZr1-xO2 (HZO) show great promise for back-end integrable storage and for neuromorphic accelerators, but their adoption is held back by the inability to scale down the HZO thickness without violating the strict thermal restrictions of the Si CMOS back end of line. In this work, we overcome this challenge and demonstrate the use of nanosecond puls

Multifaceted Deactivation Dynamics of Fe(II) N-Heterocyclic Carbene Photosensitizers

Excited state dynamics of three iron(II) carbene complexes that serve as prototype Earth-abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant differences in the dynamics between the investigated complexes down to femtosecond time scales are used to characterize fundamental differences in the depopulation of triplet metal-to-ligand charge-transfer (3MLCT) excit

Genomic Characteristics Related to Histology-based Immune Features in Breast Cancer

The immune cell component of the tumor microenvironment is an important modulator of tumor progression. In patients with breast cancer, tumor-infiltrating lymphocytes (TILs) and tertiary lymphoid structures (TLS) represent core aspects of anti-tumor immunity, both increasingly recognized for clinical relevance. In this study, we evaluated immune-related histology features using whole slide H&E

Mini Review Celiaki

Celiac disease screening in children: evaluating the evidence, benefits, and challenges TYPE Mini Review PUBLISHED 03 April 2025 DOI 10.3389/fped.2025.1562073 EDITED BY Yasin Sahin, Gaziantep Islam Science and Technology University, Türkiye REVIEWED BY Michal Kori, Kaplan Medical Center, Israel Eylem Sevinc, Karabük University, Türkiye *CORRESPONDENCE Daniel Agardh daniel.agardh@med.lu.se RECEIVED

https://www.teddy.lu.se/sites/teddy.lu.se/files/2025-05/Mini%20review%20celiaki.pdf - 2026-06-01

Forskningsstrategi SVE Tillgänglig 230315

Lunds universitets forskningsstrategi 2023–2026 FORSKNINGSSTRATEGI | 2023–2026 Forskningsstrategi LUNDS UNIVERSITET | 2023–2026 FORSKNINGSSTRATEGI | 2023–2026 3 FORSKNINGSSTRATEGI | 2023–2026FORSKNINGSSTRATEGI | 2023–2026 L unds universitet är ett anrikt universitet med stor ämnesbredd, excellent forskning och högklassig forskningsinfrastruktur. I en tid av utmaningar som kräver globalt samarbete

https://www.medarbetarwebben.lu.se/sites/medarbetarwebben.lu.se/files/2023-09/Forskningsstrategi%20SVE%20tillga%CC%88nglig%20230315.pdf - 2026-06-01

Litteraturlista FTEA13 - VT26

Litteraturlista FTEA13 - VT26 Sida 1 av 2 Filosofiska institutionen LITTERATURLISTA VT2026 FTEA13, Teoretisk filosofi, grundkurs, 30 hp Fastställd av Filosofiska institutionens studierektor 2025-05-12 Delkurs 1 – Filosofihistorisk översikt (7,5 hp) Kenny, Anthony: Västerlandets filosofi. Bokförlaget Thales, 2009. Ett urval artiklar som kommer att publiceras i Canvas Delkurs 2 – Filosofisk metod (6

https://www.ht.lu.se/media/utbildning/dokument/kurser/FTEA13/20261/Litteraturlista_FTEA13_VT2026.pdf - 2026-05-21

Förvaltningsrätt med offentlighet och sekretess, 15 hp

Förvaltningsrätt med offentlighet och sekretess, 15 hp Grade Portal Course catalogue Förvaltningsrätt med offentlighet och sekretess, 15 hp FÖRVALTNINGSRÄTT MED OFFENTLIGHET OCH SEKRETESS, 15 HP UPPDRAGSUTBILDNING | LUNDS UNIVERSITET   Förvaltningsrätt med offentlighet och sekretess ges av juridiska fakulteten vid Lunds universitet är en internetbaserad distanskurs på halvfart som ges under höst-

https://luvit.education.lu.se/LUCE/activities/activitydetails_ext.aspx?inapp=1&id=40®ionid=&cityid=&fromdate=&todate= - 2026-05-30

IT support and services

IT support and services | Student website LTH Skip to main content This site uses cookies to enhance the user experience. By continuing to use the site you agree that cookies are used according to our Cookie Policy (on the website of LTH) . Essential cookies These cookies are necessary for the website to function and cannot be turned off in our systems. These cookies do not store any personally id

https://www.student.lth.se/english/support-and-services/it-support-and-services/ - 2026-05-30