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Effect of energy bandgap and sacrificial agents of cyclopentadithiophene-based polymers for enhanced photocatalytic hydrogen evolution

A library of donor-acceptor system consisting of cyclopentadithiophene-based polymer photocatalysts have been designed and synthesized. Among all photocatalysts, the active PCPDTBSO achieved hydrogen evolution rates of 24.6 mmol h–1 g–1 with apparent quantum yields of 8.7 % at 500 nm. More importantly, combined the results of photocatalytic efficiency, apparent quantum yield, the time-resolved flu

Excited-state properties of Y-series small molecule semiconductors

The emergence of the Y series small molecule semiconductors, Y6 and its derivatives, have significantly improved the performance of polymer solar cells (PSCs). However, the excited-state properties of these Y-series small molecule semiconductors which are highly important for designing high-performance PSCs, need to be illustrated. In this work, the excited-state properties and electronic structur

Eosinophilic and Noneosinophilic Asthma : An Expert Consensus Framework to Characterize Phenotypes in a Global Real-Life Severe Asthma Cohort

Background: Phenotypic characteristics of patients with eosinophilic and noneosinophilic asthma are not well characterized in global, real-life severe asthma cohorts. Research Question: What is the prevalence of eosinophilic and noneosinophilic phenotypes in the population with severe asthma, and can these phenotypes be differentiated by clinical and biomarker variables? Study Design and Methods:

Self-Reported Shorter Than Desired Ejaculation Latency and Related Distress—Prevalence and Clinical Correlates : Results From the European Male Ageing Study

Background: Few data have looked at the occurrence and clinical correlates of self-reported shorter than desired ejaculation latency (rapid ejaculation, RE) and its related distress in the general population. Aim: To determine the prevalence and clinical correlates of self-reported RE and RE- related distress in middle age and older European men. Methods: Subjects were recruited from population sa

Outdoor air pollution from industrial chemicals causing new onset of asthma or COPD : a systematic review protocol

Background: Until today, industrial sources contribute to the multifaceted contamination of environmental air. Exposure to air pollutants has the potential to initiate and promote asthma and chronic obstructive pulmonary disease (COPD). At global scale, both entities cause the majority of about 4 million annual deaths by respiratory disease. However, we identified industrial contamination as a sub

Controlled creation of three-dimensional vortex structures in Bose--Einstein condensates using artificial magnetic fields

The physics of quantized vortex excitations in atomic Bose-Einstein condensates has been extensively studied in recent years.Although simple vortex lines are relatively easy to create, control, and measure in experiments, it is a lot more difficult to do the same for vortex ring structures.Here we suggest and explore a method for generating and controlling superfluid vortex rings, vortex ring latt

Symmetry breaking in binary Bose-Einstein condensates in the presence of an inhomogeneous artificial gauge field

We study a two component Bose-Einstein condensate in the presence of an inhomogeneous artificial gauge field. In response to this field, the condensate forms a localised vortex lattice structure that leads to a non-trivial symmetry breaking in the phase separated regime. The underlying physical mechanism can be understood by considering the energy landscape and we present a simplified model that i

Revealing vibronic coupling in chlorophyll c1 by polarization-controlled 2D electronic spectroscopy

Vibronic coupling between molecules has been recently discussed to play an important role in photosynthetic functions. Furthermore, this type of coupling between electronic states has been suggested to define photophysical properties of chlorophylls, a family of photosynthetic molecules. However, experimental investigation of vibronic coupling presents a major challenge. One subtle way to study vi

Composition Engineering in Two-Dimensional Pb-Sn-Alloyed Perovskites for Efficient and Stable Solar Cells

Environmentally friendly tin (Sn)-based metallic halide perovskites suffer from oxidation and morphological issues. Here, we demonstrate the composition engineering of Pb-Sn-alloyed two-dimensional (2D) Ruddlesden-Popper perovskites, (BA)2(MA)3Pb4-xSnxI13, for efficient and stable solar cell applications. Smooth thin films with high surface coverage are readily formed without using any additive ow

Health locus of control and mortality : a population-based prospective cohort study

Objectives: The objective of the study was to estimate associations between health locus of control (HLC) and mortality. Study design & methods: The public health survey in Scania 2008 was linked to the Swedish cause of death register. In this study of 10,757 men and 12,322 women aged 18–80 years, 421 men and 235 women died during the 5.3-year follow-up. Survival analyses were conducted. Resul

Dual Functions of O-Atoms in the g-C3N4/BO0.2N0.8Interface : Oriented Charge Flow In-Plane and Separation within the Interface to Collectively Promote Photocatalytic Molecular Oxygen Activation

The photocatalytic performance of two-dimensional materials is largely limited by the fast recombination of photogenerated charges. Herein, we design and fabricate a novel g-C3N4/BO0.2N0.8 van der Waals heterostructure to realize oriented charge flow in-plane and separation within the interface. On one hand, a B-C bond forms within the g-C3N4/BO0.2N0.8 interface after the introduction of O atoms.

Path-Dependent Self-Assembly of Magnetic Anisotropic Colloidal Peanuts

Here we present the field induced self-assembly of anisotropic colloidal particles whose shape resembles peanuts. Being made up of hematite core and silica shell, these particles align in a direction perpendicular to the applied external magnetic field. Using small-angle X-ray scattering with microradian resolution (μrad-SAXS) in sedimented samples, we have found that one can tune the self-assembl

Relating Defect Luminescence and Nonradiative Charge Recombination in MAPbI3 Perovskite Films

Nonradiative losses in semiconductors are related to defects. At cryogenic temperatures, defect-related photoluminescence (PL) at energies lower than the band-edge PL is observed in methylammonium lead triiodide perovskite. We applied multispectral PL imaging to samples prepared by two different procedures and exhibiting 1 order of magnitude different PL quantum yield (PLQY). The high-PLQY sample

Male childlessness as independent predictor of risk of cardiovascular and all-cause mortality : A population-based cohort study with more than 30 years follow-up

In a recent population-based study, an elevated risk of the Metabolic syndrome (MetS) and type 2 diabetes was found in childless men compared to those who have fathered one or more children. Therefore, by using a larger cohort of more than 22 000 men from the Malmo Preventive Project (MPP) we aimed to expand our observations in order to evaluate the metabolic profile of childless men and to evalua

Fluorescent labeling of helminth extracellular vesicles using an in vivo whole organism approach

In the last two decades, extracellular vesicles (EVs) from the three domains of life, Archaea, Bacteria and Eukaryotes, have gained increasing scientific attention. As such, the role of EVs in host-pathogen communication and immune modulation are being intensely investigated. Pivotal to EV research is the determination of how and where EVs are taken up by recipient cells and organs in vivo, which