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Dual Functions of O-Atoms in the g-C3N4/BO0.2N0.8Interface : Oriented Charge Flow In-Plane and Separation within the Interface to Collectively Promote Photocatalytic Molecular Oxygen Activation

The photocatalytic performance of two-dimensional materials is largely limited by the fast recombination of photogenerated charges. Herein, we design and fabricate a novel g-C3N4/BO0.2N0.8 van der Waals heterostructure to realize oriented charge flow in-plane and separation within the interface. On one hand, a B-C bond forms within the g-C3N4/BO0.2N0.8 interface after the introduction of O atoms.

Path-Dependent Self-Assembly of Magnetic Anisotropic Colloidal Peanuts

Here we present the field induced self-assembly of anisotropic colloidal particles whose shape resembles peanuts. Being made up of hematite core and silica shell, these particles align in a direction perpendicular to the applied external magnetic field. Using small-angle X-ray scattering with microradian resolution (μrad-SAXS) in sedimented samples, we have found that one can tune the self-assembl

Relating Defect Luminescence and Nonradiative Charge Recombination in MAPbI3 Perovskite Films

Nonradiative losses in semiconductors are related to defects. At cryogenic temperatures, defect-related photoluminescence (PL) at energies lower than the band-edge PL is observed in methylammonium lead triiodide perovskite. We applied multispectral PL imaging to samples prepared by two different procedures and exhibiting 1 order of magnitude different PL quantum yield (PLQY). The high-PLQY sample

Male childlessness as independent predictor of risk of cardiovascular and all-cause mortality : A population-based cohort study with more than 30 years follow-up

In a recent population-based study, an elevated risk of the Metabolic syndrome (MetS) and type 2 diabetes was found in childless men compared to those who have fathered one or more children. Therefore, by using a larger cohort of more than 22 000 men from the Malmo Preventive Project (MPP) we aimed to expand our observations in order to evaluate the metabolic profile of childless men and to evalua

Fluorescent labeling of helminth extracellular vesicles using an in vivo whole organism approach

In the last two decades, extracellular vesicles (EVs) from the three domains of life, Archaea, Bacteria and Eukaryotes, have gained increasing scientific attention. As such, the role of EVs in host-pathogen communication and immune modulation are being intensely investigated. Pivotal to EV research is the determination of how and where EVs are taken up by recipient cells and organs in vivo, which

2-Terminal CIGS-perovskite tandem cells : A layer by layer exploration

This paper focuses on the development of 2-terminal CIGS-perovskite tandem solar cells by exploring a range of stack sequences and synthetic procedures for depositing the associated layers. In the end, we converged at a stack sequence composed of SLG/Mo/CIGS/CdS/i-ZnO/ZnO:Al/NiO/PTAA/Perovskite/LiF/PCBM/SnO2/ITO. With this architecture, we reached performances only about 1% lower than the correspo

Positivity of entropy production for the three-level maser

Entropy production is a key concept of thermodynamics and allows one to analyze the operation of engines. For the Scovil-Schulz-DuBois heat engine, the archetypal three-level thermal maser coupled to thermal baths, it was argued that the common definition of heat flow may provide negative entropy production for certain parameters [Boukobza and Tannor, Phys. Rev. Lett. 98, 240601 (2007)PRLTAO0031-9

Immune modulation via T regulatory cell enhancement : Disease-modifying therapies for autoimmunity and their potential for chronic allergic and inflammatory diseases—An EAACI position paper of the Task Force on Immunopharmacology (TIPCO)

Therapeutic advances using targeted biologicals and small-molecule drugs have achieved significant success in the treatment of chronic allergic, autoimmune, and inflammatory diseases particularly for some patients with severe, treatment-resistant forms. This has been aided by improved identification of disease phenotypes. Despite these achievements, not all severe forms of chronic inflammatory and

Observing the emergence of a quantum phase transition shell by shell

Many-body physics describes phenomena that cannot be understood by looking only at the constituents of a system1. Striking examples are broken symmetry, phase transitions and collective excitations2. To understand how such collective behaviour emerges as a system is gradually assembled from individual particles has been a goal in atomic, nuclear and solid-state physics for decades3–6. Here we obse

Occupational exposure to whole-body vibrations and pregnancy complications : A nationwide cohort study in Sweden

Objectives Pregnancy complications are common contributors to perinatal mortality and morbidity. Still, the cause(s) of gestational hypertensive disorders and diabetes are largely unknown. Some occupational exposures have been inconsistently associated with pregnancy complications, but exposure to whole-body vibrations (WBV) has been largely overlooked even though it has been associated with adver

The implications of an aging population and increased obesity for knee arthroplasty rates in Sweden : a register-based study

Background and purpose — Total knee arthroplasty (TKA) has increased substantially in Sweden. We quantified the relative risk for TKA in the Swedish population for different BMI categories and age groups to investigate whether the continued increase in TKA is attributable to increased prevalence of obesity and elderly people in the population, and to put forward model predictions for coming needs

Variation and trends in reasons for knee replacement revision : a multi-registry study of revision burden

Background and purpose — Studies describing time-related change in reasons for knee replacement revision have been limited to single regions or institutions, commonly analyze only 1st revisions, and may not reflect true caseloads or findings from other areas. We used revision procedure data from 3 arthroplasty registries to determine trends and differences in knee replacement revision diagnoses. P

Optical Force-Induced Dynamics of Assembling, Rearrangement, and Three-Dimensional Pistol-like Ejection of Microparticles at the Solution Surface

Optical trapping and assembling dynamics of polystyrene microparticles (MPs) of 1 μm in diameter are studied at its solution-air surface using a widefield microscope. Upon switching on the intense 1064 nm laser, the MPs are gathered, forming a single concentric circle (CC)-like assembly larger than the focus. It consists of a few tens of MPs, and the central part of the assembly shows structural c

Tuning lipid structure by bile salts: Hexosomes for topical administration of catechin

The delivery of bio-active molecules through the skin is challenging given the complex structure of its outer layer, the stratum corneum. Here we explore the possibility to encapsulate natural compounds into nanocarriers containing permeation enhancers that can affect the fluidity of the stratum corneum lipids. This approach is expected to facilitate dermal or transdermal release. For this purpose

Tailoring the self-assembly, interfacial properties and rheological behaviour of sugar-based surfactants

Surfactants are important ingredients in many formulated products used in everyday life. Many of these surfactants originates from fossil-based materials and degrades slowly in aquatic systems. As society strives towards having a smaller environmental footprint, surfactants that are non-toxic, biodegradable and can be synthesized from renewable raw materials need to be developed. To this end sugar

Hydrophobic and Hydrophilic Conjugated Polymer Dots as Binary Photocatalysts for Enhanced Visible-Light-Driven Hydrogen Evolution through Förster Resonance Energy Transfer

Organic semiconducting polymers exhibited promising photocatalytic behavior for hydrogen (H2) evolution, especially when prepared in the form of polymer dots (Pdots). However, the Pdot structures were formed using common nonconjugated amphiphilic polymers, which have a negative effect on charge transfer between photocatalysts and reactants and are unable to participate in the photocatalytic reacti

Plasticity in rotifer morphology induced by conflicting threats from multiple predators

One of the major research goals in ecology is to understand predator–prey interactions. However, our understanding of how prey express phenotypic plasticity in response to co-occurring multiple predators is limited in many systems. Here, we use the rotifer Brachionus calyciflorus as model organism to test how prey responds to co-occurring predators through a series of related experiments. Firstly,

Using Combinatorial Inkjet Printing for Synthesis and Deposition of Metal Halide Perovskites in Wavelength-Selective Photodetectors

Metal halide perovskites have received great attention in recent years, predominantly due to the high performance of perovskite solar cells. The versatility of the material, which allows the tunability of the bandgap, has led to its use in light-emitting diodes, photo, and X-ray detectors, among other optoelectronic device applications. Specifically in photodetectors, the tunability of the bandgap

Renewable diesel fuels and emission control strategies : Implications for occupational exposure, human health, and the environment

Combustion of fossil diesel is a major environmental problem for both the climate and human health. Renewable diesel fuels have been developed and introduced to the market to reduce the net CO2 emissions. Emission control strategies, such as aftertreatment systems, have been implemented to reduce the health hazardous particulate matter (PM) and nitrogen oxides (NOx) emissions. The overall aim of t

Field-resolved high-order sub- cycle nonlinearities in a terahertz semiconductor laser,

The exploitation of ultrafast electron dynamics in quantum cascade lasers (QCLs) holds enormous potential forintense, compact mode-locked terahertz (THz) sources, squeezed THz light, frequency mixers, and comb-basedmetrology systems. Yet the important sub-cycle dynamics have been notoriously difficult to access in operationalTHz QCLs. Here, we employ high-field THz pulses to perform the first ultr