Heterogeneous reaction between Li and anatase TiO2 nanoparticles under ultra-high vacuum
We demonstrate heterogeneous chemistry between Li and anatase TiO2 nanoparticles under UHV. The reduction of TiO2 upon formation of lithium oxide proceeds via two different schemes: one that reduces Ti4+ to Ti3+ and one that reduces Ti4+ directly to Ti2+. The second scheme sets in only after a critical degree of reduction (i.e. Li amount) has been reached (Li/Ti = 0.28) and is associated with rest
